Title: |
Cryogenic Liquid Hazards and Controls |
Publication date: |
9/17/2021 |
Effective date: |
1/29/2010 |
BRIEF
Policy Summary
This policy describes the restrictions and conditions for persons who handle cryogens or who operate cryogenic-liquid-handling systems at Lawrence Berkeley National Laboratory (Berkeley Lab). Cryogenic liquids include, but are not limited to, liquid nitrogen, liquid helium, and liquid argon.
Who Should Read This Policy
Berkeley Lab employees, visitors, affiliates, and subcontractors who handle cryogens or who operate cryogenic-liquid-handling systems at Berkeley Lab
To Read the Full Policy, Go To:
The POLICY tab on this wiki page
To Read the EH&S Program Details, Go To:
Contact Information
For assistance on cryogenic liquid applications, including safety engineering and industrial hygiene, contact:
EHS Division
Subject Matter Expert for Cryogens
Alyssa Brand
(510) 486-7246, [email protected]
For assistance with cryogenic system repairs, maintenance, and modifications, contact:
Facilities Division
Mike Botello
(510) 486-7941, [email protected]
Title: |
Cryogenic Liquid Hazards and Controls |
Publication date: |
9/17/2021 |
Effective date: |
1/29/2010 |
POLICY
A. Purpose
This policy describes the restrictions and conditions for persons who handle cryogenic liquids or who operate cryogenic-liquid-handling systems at Lawrence Berkeley National Laboratory (Berkeley Lab).
Cryogenic liquids include, but are not limited to, liquid nitrogen, liquid helium, liquid argon, liquid oxygen, and liquid hydrogen.
B. Persons Affected
Berkeley Lab employees, visitors, affiliates, and subcontractors who handle cryogenic liquids or who operate cryogenic-liquid-handling systems at the Laboratory
C. Exceptions
None
D. Policy Statement
- The primary hazards associated with cryogenic liquids are:
- Thermal hazards due to extremely low temperatures.
- Pressurization hazards due to inadequate venting.
- Oxygen deficiency due to oxygen displacement (for all cryogenic liquids except liquid oxygen).
- Additional hazards include any hazardous characteristics associated with the cryogenic liquid (e.g., flammability of hydrogen). See work processes A, B, F, and H for more details on hazards.
- Cryogenic liquids are obtained by:
- The Principal Investigator placing an order for a portable cryogenic liquid dewar through a request to the on-site chemical supplier or
- The Principal Investigator making a request to the Facilities Division to connect to or dispense from a bulk cryogenic liquid tank (the Facilities Division has responsibility for the Laboratory's bulk cryogenic systems and for their safe design, operation, and maintenance).
- Orders and facilities requests should be followed with a note or call to the Cryogenic Liquids Subject Matter Expert (SME) to start assessment processes.
- Before work with cryogenic liquids is undertaken, an oxygen-deficiency risk assessment must be conducted (Work Process C).
- Persons who handle cryogens or who operate cryogenic-liquid-handling systems at Berkeley Lab must, prior to use of either, complete training that covers:
- Awareness of hazards related to the equipment.
- Methods for controlling those hazards.
- Proper operating procedures applicable to the equipment (Work Process B).
- Ensure all hazards associated with the handling of cryogenic liquids in an area are identified and controlled (work processes C through H).
- Line management must ensure:
- Only equipment intended for cryogenic service is used.
- Equipment, commercial or otherwise, is not modified in a fashion that could defeat the designed safety features of the equipment or otherwise create an unforeseen hazard, such as inadequate venting of cryogen spaces.
- Equipment is appropriately designed, fabricated, and used for cryogenic use (See Work Process D of ES&H Manual Chapter 29).
- Users of cryogenic systems must follow training guidance and written procedures covering:
- Operation of cryogenics systems (work processes B, D, and H).
- Use of controls for cryogenic liquid handling, including personal protective equipment (PPE) (work processes C, D, E, and G).
- Transportation of cryogenic liquids (Work Process H).
- Disposal of cryogenic materials (Work Process J).
- Reporting of incidents with cryogenic liquids (Work Process K).
E. Roles and Responsibilities
See the ES&H Manual for roles and responsibilities related to the execution of this policy's implementation.
Role |
Responsibility |
Facilities Division |
Oversees the Laboratory's bulk cryogenic systems and their safe design, operation, and maintenance |
Cryogenic Liquids SME |
Is responsible for development, approval, revision, and administration of this policy and its implementing documents |
Line Managers |
Ensure that persons within their areas of responsibility comply with this policy and its implementing documents |
Supervisors and Work Leads |
Ensure that persons within their areas of responsibility comply with this policy and its implementing documents, and in particular have completed the required training prior to beginning work |
Cryogenic Liquid Users |
Follow all guidance provided in training and Work Processes to safety use, transport, and dispose of cryogenic liquids |
F. Definitions/Acronyms
See ES&H Manual Chapter 29 for technical terms related to the details of this policy and its implementation.
Term |
Definition |
Cryogenic Liquid |
A material whose boiling point is less than 120 Kelvin (-153 degrees Celsius). The typical cryogenic materials used at Berkeley Lab include but are not limited to liquid nitrogen, liquid helium, liquid argon, liquid oxygen, and liquid hydrogen. |
G. Recordkeeping Requirements
Role |
Recordkeeping Requirement |
Subject Matter Expert |
Oxygen-Deficiency Risk Assessments |
Subject Matter Expert |
Cryogenic Safety Training Records |
Hazardous Waste Office |
Hazardous Waste Manifests |
H. Implementing Documents
Document Number |
EH&S Reference Numbers |
Title |
Type |
07.07.009.001 |
Ch. 29 |
Safe Handling of Cryogenic Liquids |
Program |
07.07.026.001 |
Ch. 7 |
Pressure Safety |
Program |
07.07.009.002 |
Ch. 29, Work Process A |
General Cryogen Information |
Process |
07.07.009.003 |
Ch. 29, Work Process B |
Working with Cryogens and Cryogen Systems |
Process |
07.07.009.004 |
Ch. 29, Work Process C |
Oxygen Deficiency Risk Assessment |
Process |
07.07.009.005 |
Ch. 29, Work Process D |
Engineering Controls and System Requirements |
Process |
07.07.009.006 |
Ch. 29, Work Process E |
Personal Protective Equipment for Cryogen Handling |
Process |
07.07.009.007 |
Ch. 29, Work Process F |
Training |
Process |
07.07.009.008 |
Ch 29, Work Process G |
Verification of Controls |
Process |
07.07.009.009 |
Ch 29, Work Process H |
Work Procedures for Handling and Transportation |
Process |
07.07.009.010 |
Ch 29, Work Process I |
First Aid for Cryogen Contact |
Process |
07.07.009.011 |
Ch 29, Work Process J |
Waste Disposal |
Process |
07.07.009.012 |
Ch 29, Work Process K |
Reporting Incidents: ES&H Documentation and Reporting/Notification |
Process |
I. Contact Information
For assistance on cryogenic liquid applications, including safety engineering and industrial hygiene, contact:
EH&S Subject Matter Expert for Cryogens
Alyssa Brand
(510) 486-7246, [email protected]
For assistance with cryogenic system repairs, maintenance, and modifications, contact:
Facilities Division
Mike Botello
(510) 486-7941, [email protected]
J. Revision History
Date |
Revision |
By Whom |
Revision Description |
Section(s) Affected |
Change Type |
9/10/13 |
1.1 |
S. Robinson |
Reviewed 9/6/2013, no changes |
Publ & Next Review Dates |
Minor |
1/2/2012 |
1 |
J. Dionne |
Rewrite for wiki |
all |
Minor |
9/17/2021 |
1.2 |
A. Brand |
Periodic review |
All |
Minor |
DOCUMENT INFORMATION
Title: |
Cryogenic Liquid Hazards and Controls |
Document number |
07.07.009.000 |
Revision number |
1.2 |
Publication date: |
9/17/2021 |
Effective date: |
1/29/2010 |
Next review date: |
9/17/2026 |
Policy Area: |
Industrial Hygiene and Safety |
RPM Section (home) |
ESH |
RPM Section (cross-reference) |
None |
Functional Division |
EH&S |
Prior reference information (optional) |
ES&H Manual Ch. 29 |
Source Requirements Documents
- 8 CCR Chapter 4, Subchapter 7, General Industry Safety Orders
- 10 CFR 851, Worker Safety and Health Program
- ANSI/ASME B31.3, Process Piping
- ASME Section VIII Division 1, Pressure Vessels
- CGA P-12, Safe Handling of Cryogenic Liquids
- Compressed Gas Association, Pamphlet P-12, Safe Handling of Cryogenic Liquids
- Compressed Gas Association, Pamphlet P-12, Safe Handling of Cryogenic Liquids, 6.7
- NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals, Chapter 10, Compressed and Liquefied Gases
- NFPA 55, Standard for the Storage, Use, and Handling of Compressed Gases and Cryogenic Liquids in Portable and Stationary Containers, Cylinders, and Tanks
- Public Law 91-596
- International Fire Code (IFC)
Other References
- British Cryogenics Council, Safety Panel, Cryogenics Safety Manual
- Edeskuty, F. J., and W. F. Stewart, "Safety in the Handling of Cryogenic Fluids," 1996, Plenum Press
- Timmerhaus, K. D., and T. M. Flynn, "Cryogenic Process Engineering," 1989, Plenum Press