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idCryogenic Liquid Hazards and Controls
Card
labelBrief

Title:

Cryogenic Liquid Hazards and Controls

Publication date:

9/17/2021

Effective date:

1/29/2010

BRIEF

Policy Summary

This policy describes the restrictions and conditions for persons who handle cryogens or who operate cryogenic-liquid-handling systems at Lawrence Berkeley National Laboratory (Berkeley Lab). Cryogenic liquids include, but are not limited to, liquid nitrogen, liquid helium, and liquid argon.

Who Should Read This Policy

Berkeley Lab employees, visitors, affiliates, and subcontractors who handle cryogens or who operate cryogenic-liquid-handling systems at Berkeley Lab

To Read the Full Policy, Go To:

The POLICY tab on this wiki page

To Read the EH&S Program Details, Go To:

ES&H Manual Chapter 29

Contact Information

For assistance on cryogenic liquid applications, including safety engineering and industrial hygiene, contact:
EHS Division
Subject Matter Expert for Cryogens
Alyssa Brand
(510) 486-7246, [email protected]

For assistance with cryogenic system repairs, maintenance, and modifications, contact:
Facilities Division
Mike Botello
(510) 486-7941, [email protected]

Card
labelPolicy

Title:

Cryogenic Liquid Hazards and Controls

Publication date:

9/17/2021

Effective date:

1/29/2010

POLICY

A. Purpose

This policy describes the restrictions and conditions for persons who handle cryogenic liquids or who operate cryogenic-liquid-handling systems at Lawrence Berkeley National Laboratory (Berkeley Lab).
Cryogenic liquids include, but are not limited to, liquid nitrogen, liquid helium, liquid argon, liquid oxygen, and liquid hydrogen.

B. Persons Affected

Berkeley Lab employees, visitors, affiliates, and subcontractors who handle cryogenic liquids or who operate cryogenic-liquid-handling systems at the Laboratory

C. Exceptions

None

D. Policy Statement

  1. The primary hazards associated with cryogenic liquids are:
    1. Thermal hazards due to extremely low temperatures.
    2. Pressurization hazards due to inadequate venting.
    3. Oxygen deficiency due to oxygen displacement (for all cryogenic liquids except liquid oxygen).
  2. Additional hazards include any hazardous characteristics associated with the cryogenic liquid (e.g., flammability of hydrogen). See work processes A, B, F, and H for more details on hazards.
  3. Cryogenic liquids are obtained by:
    1. The Principal Investigator placing an order for a portable cryogenic liquid dewar through a request to the on-site chemical supplier or
    2. The Principal Investigator making a request to the Facilities Division to connect to or dispense from a bulk cryogenic liquid tank (the Facilities Division has responsibility for the Laboratory's bulk cryogenic systems and for their safe design, operation, and maintenance).
  4. Orders and facilities requests should be followed with a note or call to the Cryogenic Liquids Subject Matter Expert (SME) to start assessment processes.
  5. Before work with cryogenic liquids is undertaken, an oxygen-deficiency risk assessment must be conducted (Work Process C).
  6. Persons who handle cryogens or who operate cryogenic-liquid-handling systems at Berkeley Lab must, prior to use of either, complete training that covers:
    • Awareness of hazards related to the equipment.
    • Methods for controlling those hazards.
    • Proper operating procedures applicable to the equipment (Work Process B).
  7. Ensure all hazards associated with the handling of cryogenic liquids in an area are identified and controlled (work processes C through H).
  8. Line management must ensure:
    1. Only equipment intended for cryogenic service is used.
    2. Equipment, commercial or otherwise, is not modified in a fashion that could defeat the designed safety features of the equipment or otherwise create an unforeseen hazard, such as inadequate venting of cryogen spaces.
    3. Equipment is appropriately designed, fabricated, and used for cryogenic use (See Work Process D of ES&H Manual Chapter 29).
  9. Users of cryogenic systems must follow training guidance and written procedures covering:
    1. Operation of cryogenics systems (work processes B, D, and H).
    2. Use of controls for cryogenic liquid handling, including personal protective equipment (PPE) (work processes C, D, E, and G).
    3. Transportation of cryogenic liquids (Work Process H).
    4. Disposal of cryogenic materials (Work Process J).
    5. Reporting of incidents with cryogenic liquids (Work Process K).

E. Roles and Responsibilities

See the ES&H Manual for roles and responsibilities related to the execution of this policy's implementation.

Role

Responsibility

Facilities Division

Oversees the Laboratory's bulk cryogenic systems and their safe design, operation, and maintenance

Cryogenic Liquids SME

Is responsible for development, approval, revision, and administration of this policy and its implementing documents

Line Managers

Ensure that persons within their areas of responsibility comply with this policy and its implementing documents

Supervisors and Work Leads

Ensure that persons within their areas of responsibility comply with this policy and its implementing documents, and in particular have completed the required training prior to beginning work

Cryogenic Liquid Users

Follow all guidance provided in training and Work Processes to safety use, transport, and dispose of cryogenic liquids

F. Definitions/Acronyms

See ES&H Manual Chapter 29 for technical terms related to the details of this policy and its implementation.

Term

Definition

Cryogenic Liquid

A material whose boiling point is less than 120 Kelvin (-153 degrees Celsius). The typical cryogenic materials used at Berkeley Lab include but are not limited to liquid nitrogen, liquid helium, liquid argon, liquid oxygen, and liquid hydrogen.

G. Recordkeeping Requirements

Role

Recordkeeping Requirement

Subject Matter Expert

Oxygen-Deficiency Risk Assessments

Subject Matter Expert

Cryogenic Safety Training Records

Hazardous Waste Office

Hazardous Waste Manifests

H. Implementing Documents

Document Number

EH&S Reference Numbers

Title

Type

07.07.009.001

Ch. 29

Safe Handling of Cryogenic Liquids

Program

07.07.026.001

Ch. 7

Pressure Safety

Program

07.07.009.002

Ch. 29, Work Process A

General Cryogen Information

Process

07.07.009.003

Ch. 29, Work Process B

Working with Cryogens and Cryogen Systems

Process

07.07.009.004

Ch. 29, Work Process C

Oxygen Deficiency Risk Assessment

Process

07.07.009.005

Ch. 29, Work Process D

Engineering Controls and System Requirements

Process

07.07.009.006

Ch. 29, Work Process E

Personal Protective Equipment for Cryogen Handling

Process

07.07.009.007

Ch. 29, Work Process F

Training

Process

07.07.009.008

Ch 29, Work Process G

Verification of Controls

Process

07.07.009.009

Ch 29, Work Process H

Work Procedures for Handling and Transportation

Process

07.07.009.010

Ch 29, Work Process I

First Aid for Cryogen Contact

Process

07.07.009.011

Ch 29, Work Process J

Waste Disposal

Process

07.07.009.012

Ch 29, Work Process K

Reporting Incidents: ES&H Documentation and Reporting/Notification

Process

I. Contact Information

For assistance on cryogenic liquid applications, including safety engineering and industrial hygiene, contact:
EH&S Subject Matter Expert for Cryogens
Alyssa Brand
(510) 486-7246, [email protected]

For assistance with cryogenic system repairs, maintenance, and modifications, contact:
Facilities Division
Mike Botello
(510) 486-7941, [email protected]

J. Revision History

Date

Revision

By Whom

Revision Description

Section(s) Affected

Change Type

9/10/13

1.1

S. Robinson

Reviewed 9/6/2013, no changes

Publ & Next Review Dates

Minor

1/2/2012

1

J. Dionne

Rewrite for wiki

all

Minor

9/17/2021

1.2

A. Brand

Periodic review

All

Minor

Card
labelDocument Information

DOCUMENT INFORMATION

Title:

Cryogenic Liquid Hazards and Controls

Document number

07.07.009.000

Revision number

1.2

Publication date:

9/17/2021

Effective date:

1/29/2010

Next review date:

9/17/2026

Policy Area:

Industrial Hygiene and Safety

RPM Section (home)

ESH

RPM Section (cross-reference)

None

Functional Division

EH&S

Prior reference information (optional)

ES&H Manual Ch. 29

Source Requirements Documents

  • 8 CCR Chapter 4, Subchapter 7, General Industry Safety Orders
  • 10 CFR 851, Worker Safety and Health Program
  • ANSI/ASME B31.3, Process Piping
  • ASME Section VIII Division 1, Pressure Vessels
  • CGA P-12, Safe Handling of Cryogenic Liquids
  • Compressed Gas Association, Pamphlet P-12, Safe Handling of Cryogenic Liquids
  • Compressed Gas Association, Pamphlet P-12, Safe Handling of Cryogenic Liquids, 6.7
  • NFPA 45 Standard on Fire Protection for Laboratories Using Chemicals, Chapter 10, Compressed and Liquefied Gases
  • NFPA 55, Standard for the Storage, Use, and Handling of Compressed Gases and Cryogenic Liquids in Portable and Stationary Containers, Cylinders, and Tanks
  • Public Law 91-596
  • International Fire Code (IFC)

Other References

  • British Cryogenics Council, Safety Panel, Cryogenics Safety Manual
  • Edeskuty, F. J., and W. F. Stewart, "Safety in the Handling of Cryogenic Fluids," 1996, Plenum Press
  • Timmerhaus, K. D., and T. M. Flynn, "Cryogenic Process Engineering," 1989, Plenum Press
Show If
grouprpm2-admins
Card
labelAdditional Information

ADDITIONAL INFORMATION

Title:

Cryogenic Liquid Hazards and Controls

Document number

07.07.009.000

Revision number

1.2

Publication date:

9/17/2021

Effective date:

9/17/2021

Next review date:

9/17/2026

Policy Area:

Industrial Hygiene & Safety

RPM Section (home)

ESH

RPM Section (cross-reference)

None

Functional Division

EHS

Author name/contact info

J. Dionne



Revision 0 publication date

1/29/2010

Retirement date

n/a

Prior reference information (optional)

PUB-3000 Ch. 29



Inputs from more than one Functional Area?

Yes

List additional Functional Areas & contacts

Facilities Division



Inputs from more than one Policy Area?

No

List additional Policy Areas & contacts




30-day notification needed?

No

30-day start date

n/a

30-day end date

n/a



LDAP protected?

No



Need TABL reminders?

No

Frequency

n/a

Brief reminder text:

n/a



Approval Sheet for this revision received (date) [Note: author is responsible}


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  • Text, text, text

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Implementing Documents restricted to department/functional use

(optional – these will be used for tracing between requirements and associated documents)

Document number

Title





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